مواد شیمیایی جداول کنوانسیون سلاح های شیمیایی

PROTOCOL FOR NAMING COMPOUNDS IN THE OPCW CENTRAL ANALYTICAL DATABASE Technical Secretariat

A. Toxic Chemicals

    (CAS Registry number)
(1) O-Alkyl (<=C10, incl. cycloalkyl) alkyl (Me, Et, n-Pr or i-Pr)-phosphonofluoridates
e.g. Sarin: O-Isopropyl methylphosphonofluoridate (107-44-8)
Soman: O-Pinacolyl methylphosphonofluoridate (96-64-0)
(2) O-Alkyl (<=C10, incl. cycloalkyl) N,N-dialkyl (Me, Et, n-Pr or i-Pr) phosphoramidocyanidates
e.g. Tabun: O-Ethyl N,N-dimethyl phosphoramidocyanidate (77-81-6)
(3) O-Alkyl (H or <=C10, incl. cycloalkyl) S-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonothiolates and corresponding alkylated or protonated salts
e.g. VX: O-Ethyl S-2-diisopropylaminoethyl methyl phosphonothiolate (50782-69-9)
(4) Sulfur mustards:
2-Chloroethylchloromethylsulfide (2625-76-5)
Mustard gas: Bis(2-chloroethyl)sulfide (505-60-2)
Bis(2-chloroethylthio)methane (63869-13-6)
Sesquimustard: 1,2-Bis(2-chloroethylthio)ethane (3563-36-8)
1,3-Bis(2-chloroethylthio)-n-propane (63905-10-2)
1,4-Bis(2-chloroethylthio)-n-butane (142868-93-7)
1,5-Bis(2-chloroethylthio)-n-pentane (142868-94-8)
Bis(2-chloroethylthiomethyl)ether (63918-90-1)
O-Mustard: Bis(2-chloroethylthioethyl)ether (63918-89-8)
(5) Lewisites:
Lewisite 1: 2-Chlorovinyldichloroarsine (541-25-3)
Lewisite 2: Bis(2-chlorovinyl)chloroarsine (40334-69-8)
Lewisite 3: Tris(2-chlorovinyl)arsine (40334-70-1)
(6) Nitrogen mustards:
HN1: Bis(2-chloroethyl)ethylamine (538-07-8)
HN2: Bis(2-chloroethyl)methylamine (51-75-2)
HN3: Tris(2-chloroethyl)amine (555-77-1)
(7) Saxitoxin (35523-89-8)
(8) Ricin (9009-86-3)

B. Precursors

    (CAS Registry number)
(9) Alkyl (Me, Et, n-Pr or i-Pr) phosphonyldifluorides
e.g. DF: Methylphosphonyldifluoride (676-99-3)
(10) O-Alkyl (H or <=C10, incl. cycloalkyl) O-2-dalkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonites and corresponding alkylated or protonated salts
e.g. QL: O-Ethyl O-2-diisopropylaminoethyl methylphosphonite (57856-11-8)
(11) Chlorosarin: O-Isopropyl methylphosphonochloridate (1445-76-7)
(12) Chlorosoman: O-Pinacolyl methylphosphonochloridate (7040-57-5)

A. Toxic Chemicals

    (CAS Registry number)
(1) Amiton: O,O-Diethyl S-[2-(diethylamino)ethyl] phosphorothiolate (78-53-5)
and corresponding alkylated or protonated salts
(2) PFIB: 1,1,3,3,3-Pentafluoro-2-(trifluoromethyl)-1-propene (382-21-8)
(3) BZ: 3-Quinuclidinyl benzilate (*) (6581-06-2)

B. Precursors

    (CAS Registry number)
(4) Chemicals, except for those listed in Schedule 1, containing a phosphorus atom to which is bonded one methyl, ethyl or propyl (normal or iso) group but not further carbon atoms,
e.g Methylphosphonyl dichloride (676-97-1)
Dimethyl methylphosphonate (756-79-6)
Exemption: Fonofos: O-Ethyl S-phenyl ethylphosphonothiolothionate (944-22-9)
(5) N,N-Dialkyl (Me, Et, n-Pr or i-Pr) phosphoramidic dihalides
(6) Dialkyl (Me, Et, n-Pr or i-Pr) N,N-dialkyl (Me, Et, n-Pr or i-Pr)-phosphoramidates
(7) Arsenic trichloride (7784-34-1)
(8) 2,2-Diphenyl-2-hydroxyacetic acid (76-93-7)
(9) Quinuclidin-3-ol (1619-34-7)
(10) N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethyl-2-chlorides and corresponding protonated salts
(11) N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethane-2-ols and corresponding protonated salts
Exemptions: N,N-Dimethylaminoethanol (108-01-0)
and corresponding protonated salts
N,N-Diethylaminoethanol (100-37-8)
and corresponding protonated salts
(12) N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethane-2-thiols and corresponding protonated salts
(13) Thiodiglycol: Bis(2-hydroxyethyl)sulfide (111-48-8)
(14) Pinacolyl alcohol: 3,3-Dimethylbutan-2-ol (464-07-3)

A. Toxic Chemicals

    (CAS Registry number)
(1) Phosgene: Carbonyl dichloride (75-44-5)
(2) Cyanogen chloride (506-77-4)
(3) Hydrogen cyanide (74-90-8)
(4) Chloropicrin: Trichloronitromethane (76-06-2)

B. Precursors

    (CAS Registry number)
(5) Phosphorus oxychloride (10025-87-3)
(6) Phosphorus trichloride (7719-12-2)
(7) Phosphorus pentachloride (10026-13-8)
(8) Trimethyl phosphite (121-45-9)
(9) Triethyl phosphite (122-52-1)
(10) Dimethyl phosphite (868-85-9)
(11) Diethyl phosphite (762-04-9)
(12) Sulfur monochloride (10025-67-9)
(13) Sulfur dichloride (10545-99-0)
(14) Thionyl chloride (7719-09-7)
(15) Ethyldiethanolamine (139-87-7)
(16) Methyldiethanolamine (105-59-9)
(17) Triethanolamine (102-71-6)

EXAMPLES OF NAMES OF SCHEDULED COMPOUNDS

Schedule Name
1.A.01 Alkyl alkylphosphonofluoridate
1.A.02 Alkyl N,N-dialkylphosphoramidocyanidate
1.A.03 Alkyl S-2-dialkylaminoethyl alkylphosphonothiolate
Alkyl S-trialkylammoniumethyl alkylphosphonothiolate halide (i.e. chloride, iodide)
1.A.04 2-Chloroethylchloromethylsulfide
Bis(2-chloroethyl)sulfide
Bis(2-chloroethylthio)methane
1,2-Bis(2-chloroethylthio)ethane
1,3-Bis(2-chloroethylthio)propane
1,4-Bis(2-chloroethylthio)butane
1,5-Bis(2-chloroethylthio)pentane
Bis(2-chloroethylthiomethyl)ether
Bis(2-chloroethylthioethyl)ether
1.A.05 2-Chlorovinyldichloroarsine
Bis(2-chlorovinyl)chloroarsine
Tris(2-chlorovinyl)arsine
1.A.06 Bis(2-chloroethyl)ethylamine
Bis(2-chloroethyl)methylamine
Tris(2-chloroethyl)amine
1.A.07 Saxitoxin
1.A.08 Ricin
1.B.09 Alkylphosphonic difluoride
1.B.10 Alkyl 2-dialkylaminoethyl alkylphosphonite
1.B.11 Isopropyl methylphosphonochloridate
1.B.12 Pinacolyl methylphosphonochloridate
2.A.01 O,O-Diethyl S-2-diethylaminoethyl phosphorothiolate
2.A.02 1,1,3,3,3-Pentafluoro-2-(trifluoromethyl)-1-propene
2.A.03 3-Quinuclidinyl benzilate
2.B.04 To avoid any confusion the O and S groups, should be indicated in esters when sulfur is present.
Examples
Methylphosphonothioic acid [(CH3P(=S)(OH) 2]
O-Ethyl methylphosphonothionate [(C2H5O)P(=S)(CH3)(OH)]
O,O-Diethyl methylphosphonothionate [(C2H5O)2P(=S)(CH3)]
O-Propyl O-trimethylsilyl propylphosphonothionate
O-Ethyl S-ethyl methylphosphonothiolate [(C2H5O)P(=O)(CH3)(SC2H5)]
S-Ethyl O-methyl methylphosphonothiolate
O-Ethyl S-2-methylthioethyl methylphosphonothiolate
O-Ethyl S-ethyl methylphosphonothiolothionate
[(C2H5O)P(=S)(CH3)(SC2H5)]
Schedule Name
Bis(S-sec-butyl) methylphosphonodithiolate
O-Ethyl methylphosphonothionochloridate [(C2H5O)P(=S)(CH3)(Cl)]
Methylphosphonous dichloride (CH3P-Cl2)
Methylphosphonic dichloride [(CH3P(=O)-Cl2)]
Methylphosphonothioic dichloride [(CH3P(=S)-Cl2)]
Dimethyl methylphosphonate
Bis(1,2-dimethylpropyl) methylphosphonate
Benzyl 1,2-dimethylpropyl ethylphosphonate
Methyl methylphosphonate instead of methyl methylphosphonic acid
Methylphosphonic acid
Isobutyl methylphosphonochloridate
Isopropyl methylphosphonoazidate
2-Diisopropylaminoethyl methylphosphinate [(i-C3H7)2N-CH2CH2-O- P(=O)(H)(CH3)]
Methyl 2-diethylaminoethyl methylphosphonate
O-Ethyl S-2-dibutylaminoethyl methylphosphonothiolate
Bis(S-2-diethylaminoethyl) methylphosphonodithiolate
O-Ethyl S-3-dimethylaminopropyl methylphosphonothiolate
Diethyl methylphosphonite [(C2H5O) 2P(CH3)]
Dicyclohexyl dimethylpyrophosphonate [(C6H11O)(CH3)P(=O)-O- P(=O)(CH3)(C6H11O)]
Dicyclohexyl dimethylpyrophosphonodithionate [(C6H11O)(CH3)P(=S)- O-P(=S)(CH3)(C6H11O)]
2.B.05 N,N-Dialkylphosphoramidic dihalide
2.B.06 Dialkyl N,N-dialkylphosphoramidate
Dimethyl N-ethyl-N-methylphosphoramidate
2.B.07 Arsenic trichloride
2.B.08 2,2-Diphenyl-2-hydroxyacetic acid
2.B.09 3-Quinuclidinol
2.B.10 2-(N,N-Dialkylamino)ethylchloride
2-(N-Ethyl-N-methylamino)ethylchloride
2.B.11 2-(N,N-Dialkylamino)ethanol
2-(N-Ethyl-N-methylamino)ethanol
2.B.12 2-(N,N-Dialkylamino)ethanethiol
2-(N-Ethyl-N-methylamino)ethanethiol
2.B.13 Bis(2-hydroxyethyl)sulfide
2.B.14 3,3-Dimethyl-2-butanol
3.A.01 Carbonyl dichloride
3.A.02 Cyanogen chloride
3.A.03 Hydrogen cyanide
3.A.04 Trichloronitromethane
3.B.05 Phosphorus oxychloride
3.B.06 Phosphorus trichloride
3.B.07 Phosphorus pentachloride
3.B.08 Trimethyl phosphate
Schedule Name
3.B.09 Triethyl phosphate
3.B.10 Dimethyl phosphate
3.B.11 Diethyl phosphate
3.B.12 Sulfur monochloride
3.B.13 Sulfur dichloride
3.B.14 Thionyl chloride
3.B.15 Ethyldiethanolamine
3.B.16 Methyldiethanolamine
3.B.17 Triethanolamine

EXAMPLES OF NAMES FOR DERIVATIVES (D.S.)

D.S. Type of Name
1.A.05 2-(2-Chlorovinyl)-5-methyl-1,3,2-benzodithiarsole
2.B.08 Bis(trimethylsilyl)benzilate
2.B.09 3-Quinuclidinyl trimethylsilyl ether
2.B.07 2-Chloro-5-methyl-1,3,2-benzodithiarsole
2.B.11 N,N-Dialkyl-N-(2-trimethylsilyloxyethyl)amine
N,N-Dialkyl-N-(2-tert-butyldimethylsilyloxyethyl)amine
2.B.12 N,N-Dialkyl-N-(2-trimethylsilylthioethyl)amine
2.B.13 Bis(2-trimethylsilyloxyethyl)sulphide
3.B.15 Bis(2-trimethylsilyloxyethyl)ethylamine
3.B.16 Bis(2-trimethylsilyloxyethyl)methylamine
3.B.17 Tris(2-trimethylsilyloxyethyl)amine
Tris(2-tert-butyldimethylsilyloxyethyl)amine

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