PROTOCOL FOR NAMING COMPOUNDS IN THE OPCW CENTRAL ANALYTICAL DATABASE | Technical Secretariat | |
A. Toxic Chemicals
(CAS Registry number) | ||
(1) | O-Alkyl (<=C10, incl. cycloalkyl) alkyl (Me, Et, n-Pr or i-Pr)-phosphonofluoridates | |
e.g. Sarin: | O-Isopropyl methylphosphonofluoridate | (107-44-8) |
Soman: | O-Pinacolyl methylphosphonofluoridate | (96-64-0) |
(2) | O-Alkyl (<=C10, incl. cycloalkyl) N,N-dialkyl (Me, Et, n-Pr or i-Pr) phosphoramidocyanidates | |
e.g. Tabun: | O-Ethyl N,N-dimethyl phosphoramidocyanidate | (77-81-6) |
(3) | O-Alkyl (H or <=C10, incl. cycloalkyl) S-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonothiolates and corresponding alkylated or protonated salts | |
e.g. VX: | O-Ethyl S-2-diisopropylaminoethyl methyl phosphonothiolate | (50782-69-9) |
(4) | Sulfur mustards: | |
2-Chloroethylchloromethylsulfide | (2625-76-5) | |
Mustard gas: Bis(2-chloroethyl)sulfide | (505-60-2) | |
Bis(2-chloroethylthio)methane | (63869-13-6) | |
Sesquimustard: 1,2-Bis(2-chloroethylthio)ethane | (3563-36-8) | |
1,3-Bis(2-chloroethylthio)-n-propane | (63905-10-2) | |
1,4-Bis(2-chloroethylthio)-n-butane | (142868-93-7) | |
1,5-Bis(2-chloroethylthio)-n-pentane | (142868-94-8) | |
Bis(2-chloroethylthiomethyl)ether | (63918-90-1) | |
O-Mustard: Bis(2-chloroethylthioethyl)ether | (63918-89-8) | |
(5) | Lewisites: | |
Lewisite 1: 2-Chlorovinyldichloroarsine | (541-25-3) | |
Lewisite 2: Bis(2-chlorovinyl)chloroarsine | (40334-69-8) | |
Lewisite 3: Tris(2-chlorovinyl)arsine | (40334-70-1) | |
(6) | Nitrogen mustards: | |
HN1: Bis(2-chloroethyl)ethylamine | (538-07-8) | |
HN2: Bis(2-chloroethyl)methylamine | (51-75-2) | |
HN3: Tris(2-chloroethyl)amine | (555-77-1) | |
(7) | Saxitoxin | (35523-89-8) |
(8) | Ricin | (9009-86-3) |
B. Precursors
(CAS Registry number) | ||
(9) | Alkyl (Me, Et, n-Pr or i-Pr) phosphonyldifluorides | |
e.g. DF: | Methylphosphonyldifluoride | (676-99-3) |
(10) | O-Alkyl (H or <=C10, incl. cycloalkyl) O-2-dalkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonites and corresponding alkylated or protonated salts | |
e.g. QL: | O-Ethyl O-2-diisopropylaminoethyl methylphosphonite | (57856-11-8) |
(11) | Chlorosarin: O-Isopropyl methylphosphonochloridate | (1445-76-7) |
(12) | Chlorosoman: O-Pinacolyl methylphosphonochloridate | (7040-57-5) |
A. Toxic Chemicals
(CAS Registry number) | ||
(1) | Amiton: O,O-Diethyl S-[2-(diethylamino)ethyl] phosphorothiolate | (78-53-5) |
and corresponding alkylated or protonated salts | ||
(2) | PFIB: 1,1,3,3,3-Pentafluoro-2-(trifluoromethyl)-1-propene | (382-21-8) |
(3) | BZ: 3-Quinuclidinyl benzilate (*) | (6581-06-2) |
B. Precursors
(CAS Registry number) | ||
(4) | Chemicals, except for those listed in Schedule 1, containing a phosphorus atom to which is bonded one methyl, ethyl or propyl (normal or iso) group but not further carbon atoms, | |
e.g | Methylphosphonyl dichloride | (676-97-1) |
Dimethyl methylphosphonate | (756-79-6) | |
Exemption: Fonofos: | O-Ethyl S-phenyl ethylphosphonothiolothionate | (944-22-9) |
(5) | N,N-Dialkyl (Me, Et, n-Pr or i-Pr) phosphoramidic dihalides | |
(6) | Dialkyl (Me, Et, n-Pr or i-Pr) N,N-dialkyl (Me, Et, n-Pr or i-Pr)-phosphoramidates | |
(7) | Arsenic trichloride | (7784-34-1) |
(8) | 2,2-Diphenyl-2-hydroxyacetic acid | (76-93-7) |
(9) | Quinuclidin-3-ol | (1619-34-7) |
(10) | N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethyl-2-chlorides and corresponding protonated salts | |
(11) | N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethane-2-ols and corresponding protonated salts | |
Exemptions: | N,N-Dimethylaminoethanol | (108-01-0) |
and corresponding protonated salts | ||
N,N-Diethylaminoethanol | (100-37-8) | |
and corresponding protonated salts | ||
(12) | N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethane-2-thiols and corresponding protonated salts | |
(13) | Thiodiglycol: Bis(2-hydroxyethyl)sulfide | (111-48-8) |
(14) | Pinacolyl alcohol: 3,3-Dimethylbutan-2-ol | (464-07-3) |
A. Toxic Chemicals
(CAS Registry number) | ||
(1) | Phosgene: Carbonyl dichloride | (75-44-5) |
(2) | Cyanogen chloride | (506-77-4) |
(3) | Hydrogen cyanide | (74-90-8) |
(4) | Chloropicrin: Trichloronitromethane | (76-06-2) |
B. Precursors
(CAS Registry number) | ||
(5) | Phosphorus oxychloride | (10025-87-3) |
(6) | Phosphorus trichloride | (7719-12-2) |
(7) | Phosphorus pentachloride | (10026-13-8) |
(8) | Trimethyl phosphite | (121-45-9) |
(9) | Triethyl phosphite | (122-52-1) |
(10) | Dimethyl phosphite | (868-85-9) |
(11) | Diethyl phosphite | (762-04-9) |
(12) | Sulfur monochloride | (10025-67-9) |
(13) | Sulfur dichloride | (10545-99-0) |
(14) | Thionyl chloride | (7719-09-7) |
(15) | Ethyldiethanolamine | (139-87-7) |
(16) | Methyldiethanolamine | (105-59-9) |
(17) | Triethanolamine | (102-71-6) |
EXAMPLES OF NAMES OF SCHEDULED COMPOUNDS
Schedule | Name |
1.A.01 | Alkyl alkylphosphonofluoridate |
1.A.02 | Alkyl N,N-dialkylphosphoramidocyanidate |
1.A.03 | Alkyl S-2-dialkylaminoethyl alkylphosphonothiolate |
Alkyl S-trialkylammoniumethyl alkylphosphonothiolate halide (i.e. chloride, iodide) | |
1.A.04 | 2-Chloroethylchloromethylsulfide |
Bis(2-chloroethyl)sulfide | |
Bis(2-chloroethylthio)methane | |
1,2-Bis(2-chloroethylthio)ethane | |
1,3-Bis(2-chloroethylthio)propane | |
1,4-Bis(2-chloroethylthio)butane | |
1,5-Bis(2-chloroethylthio)pentane | |
Bis(2-chloroethylthiomethyl)ether | |
Bis(2-chloroethylthioethyl)ether | |
1.A.05 | 2-Chlorovinyldichloroarsine |
Bis(2-chlorovinyl)chloroarsine | |
Tris(2-chlorovinyl)arsine | |
1.A.06 | Bis(2-chloroethyl)ethylamine |
Bis(2-chloroethyl)methylamine | |
Tris(2-chloroethyl)amine | |
1.A.07 | Saxitoxin |
1.A.08 | Ricin |
1.B.09 | Alkylphosphonic difluoride |
1.B.10 | Alkyl 2-dialkylaminoethyl alkylphosphonite |
1.B.11 | Isopropyl methylphosphonochloridate |
1.B.12 | Pinacolyl methylphosphonochloridate |
2.A.01 | O,O-Diethyl S-2-diethylaminoethyl phosphorothiolate |
2.A.02 | 1,1,3,3,3-Pentafluoro-2-(trifluoromethyl)-1-propene |
2.A.03 | 3-Quinuclidinyl benzilate |
2.B.04 | To avoid any confusion the O and S groups, should be indicated in esters when sulfur is present. |
Examples | |
Methylphosphonothioic acid [(CH3P(=S)(OH) 2] | |
O-Ethyl methylphosphonothionate [(C2H5O)P(=S)(CH3)(OH)] | |
O,O-Diethyl methylphosphonothionate [(C2H5O)2P(=S)(CH3)] | |
O-Propyl O-trimethylsilyl propylphosphonothionate | |
O-Ethyl S-ethyl methylphosphonothiolate [(C2H5O)P(=O)(CH3)(SC2H5)] | |
S-Ethyl O-methyl methylphosphonothiolate | |
O-Ethyl S-2-methylthioethyl methylphosphonothiolate | |
O-Ethyl S-ethyl methylphosphonothiolothionate [(C2H5O)P(=S)(CH3)(SC2H5)] |
Schedule | Name |
Bis(S-sec-butyl) methylphosphonodithiolate | |
O-Ethyl methylphosphonothionochloridate [(C2H5O)P(=S)(CH3)(Cl)] | |
Methylphosphonous dichloride (CH3P-Cl2) | |
Methylphosphonic dichloride [(CH3P(=O)-Cl2)] | |
Methylphosphonothioic dichloride [(CH3P(=S)-Cl2)] | |
Dimethyl methylphosphonate | |
Bis(1,2-dimethylpropyl) methylphosphonate | |
Benzyl 1,2-dimethylpropyl ethylphosphonate | |
Methyl methylphosphonate instead of methyl methylphosphonic acid | |
Methylphosphonic acid | |
Isobutyl methylphosphonochloridate | |
Isopropyl methylphosphonoazidate | |
2-Diisopropylaminoethyl methylphosphinate [(i-C3H7)2N-CH2CH2-O- P(=O)(H)(CH3)] | |
Methyl 2-diethylaminoethyl methylphosphonate | |
O-Ethyl S-2-dibutylaminoethyl methylphosphonothiolate | |
Bis(S-2-diethylaminoethyl) methylphosphonodithiolate | |
O-Ethyl S-3-dimethylaminopropyl methylphosphonothiolate | |
Diethyl methylphosphonite [(C2H5O) 2P(CH3)] | |
Dicyclohexyl dimethylpyrophosphonate [(C6H11O)(CH3)P(=O)-O- P(=O)(CH3)(C6H11O)] | |
Dicyclohexyl dimethylpyrophosphonodithionate [(C6H11O)(CH3)P(=S)- O-P(=S)(CH3)(C6H11O)] | |
2.B.05 | N,N-Dialkylphosphoramidic dihalide |
2.B.06 | Dialkyl N,N-dialkylphosphoramidate |
Dimethyl N-ethyl-N-methylphosphoramidate | |
2.B.07 | Arsenic trichloride |
2.B.08 | 2,2-Diphenyl-2-hydroxyacetic acid |
2.B.09 | 3-Quinuclidinol |
2.B.10 | 2-(N,N-Dialkylamino)ethylchloride |
2-(N-Ethyl-N-methylamino)ethylchloride | |
2.B.11 | 2-(N,N-Dialkylamino)ethanol |
2-(N-Ethyl-N-methylamino)ethanol | |
2.B.12 | 2-(N,N-Dialkylamino)ethanethiol |
2-(N-Ethyl-N-methylamino)ethanethiol | |
2.B.13 | Bis(2-hydroxyethyl)sulfide |
2.B.14 | 3,3-Dimethyl-2-butanol |
3.A.01 | Carbonyl dichloride |
3.A.02 | Cyanogen chloride |
3.A.03 | Hydrogen cyanide |
3.A.04 | Trichloronitromethane |
3.B.05 | Phosphorus oxychloride |
3.B.06 | Phosphorus trichloride |
3.B.07 | Phosphorus pentachloride |
3.B.08 | Trimethyl phosphate |
Schedule | Name |
3.B.09 | Triethyl phosphate |
3.B.10 | Dimethyl phosphate |
3.B.11 | Diethyl phosphate |
3.B.12 | Sulfur monochloride |
3.B.13 | Sulfur dichloride |
3.B.14 | Thionyl chloride |
3.B.15 | Ethyldiethanolamine |
3.B.16 | Methyldiethanolamine |
3.B.17 | Triethanolamine |
EXAMPLES OF NAMES FOR DERIVATIVES (D.S.)
D.S. | Type of Name |
1.A.05 | 2-(2-Chlorovinyl)-5-methyl-1,3,2-benzodithiarsole |
2.B.08 | Bis(trimethylsilyl)benzilate |
2.B.09 | 3-Quinuclidinyl trimethylsilyl ether |
2.B.07 | 2-Chloro-5-methyl-1,3,2-benzodithiarsole |
2.B.11 | N,N-Dialkyl-N-(2-trimethylsilyloxyethyl)amine |
N,N-Dialkyl-N-(2-tert-butyldimethylsilyloxyethyl)amine | |
2.B.12 | N,N-Dialkyl-N-(2-trimethylsilylthioethyl)amine |
2.B.13 | Bis(2-trimethylsilyloxyethyl)sulphide |
3.B.15 | Bis(2-trimethylsilyloxyethyl)ethylamine |
3.B.16 | Bis(2-trimethylsilyloxyethyl)methylamine |
3.B.17 | Tris(2-trimethylsilyloxyethyl)amine |
Tris(2-tert-butyldimethylsilyloxyethyl)amine |
9999